Caesium bromide

Caesium bromide
Names
	IUPAC name Cesium bromide
	Other names Cesium bromide,; Caesium(I) bromide
Identifiers
CAS Number	7787-69-1 ;
3D model (JSmol)	Interactive image;
ChemSpider	22994 ;
ECHA InfoCard	100.029.209
EC Number	232-130-0;
PubChem CID	24592;
RTECS number	FK9275000;
UNII	06M25EDM3F;
CompTox Dashboard (EPA)	DTXSID8064854 ;
	InChI InChI=1S/BrH.Cs/h1H;/q;+1/p-1 Key: LYQFWZFBNBDLEO-UHFFFAOYSA-M ; InChI=1/BrH.Cs/h1H;/q;+1/p-1 Key: LYQFWZFBNBDLEO-REWHXWOFAA;
	SMILES [Cs+].[Br-];
Properties
Chemical formula	CsBr
Molar mass	212.809 g/mol
Appearance	White solid
Density	4.43 g/cm3
Melting point	636 °C (1,177 °F; 909 K)
Boiling point	1,300 °C (2,370 °F; 1,570 K)
Solubility in water	1230 g/L (25 °C) Disputed. 420 g/L (11 °C) See References; 560 /L (15°C); 1020 g/L (28.5 °C); 1180 g/L (31 °C); 1240 g/L (32.5 °C); 1380 g/L (35 °C)
Magnetic susceptibility (χ)	-67.2·10−6 cm3/mol
Refractive index (nD)	1.8047 (0.3 μm); 1.6974 (0.59 μm); 1.6861 (0.75 μm); 1.6784 (1 μm); 1.6678 (5 μm); 1.6439 (20 μm)
Structure
Crystal structure	CsCl, cP2
Space group	Pm3m, No. 221
Lattice constant	a = 0.4291 nm
Lattice volume (V)	0.0790 nm3
Formula units (Z)	1
Coordination geometry	Cubic (Cs+); Cubic (Br−)
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302, H315, H319, H335
Precautionary statements	P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)	2 0 0
Flash point	Non-flammable
	Lethal dose or concentration (LD, LC):
LD50 (median dose)	1400 mg/kg (oral, rat)
Related compounds
Other anions	Caesium fluoride; Caesium chloride; Caesium iodide; Caesium astatide
Other cations	Sodium bromide; Potassium bromide; Rubidium bromide; Francium bromide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Caesium bromide or cesium bromide is an ionic compound of caesium and bromine with the chemical formula CsBr. It is a white or transparent solid with melting point at 636 °C that readily dissolves in water. Its bulk crystals have the cubic CsCl structure, but the structure changes to the rocksalt type in nanometer-thin film grown on mica, LiF, KBr or NaCl substrates.^[6]

Synthesis

Caesium bromide can be prepared via following reactions:

Neutralization:

CsOH (aq) + HBr (aq) → CsBr (aq) + H₂O (l)

Cs₂(CO₃) (aq) + 2 HBr (aq) → 2 CsBr (aq) + H₂O (l) + CO₂ (g)

Direct synthesis:

2 Cs (s) + Br₂ (g) → 2 CsBr (s)

The direct synthesis is a vigorous reaction of caesium with bromine. Due to its high cost, it is not used for preparation.

Uses

Caesium bromide is sometimes used in optics as a beamsplitter component in wide-band spectrophotometers.

References

^ ^a ^b ^c ^d ^e Haynes, p. 4.57
^ Haynes, p. 4.132
^ Haynes, p. 10.240
^ Vallin, J.; Beckman, O.; Salama, K. (1964). "Elastic Constants of CsBr and CsI from 4.2K to Room Temperature". Journal of Applied Physics. 35 (4): 1222. Bibcode:1964JAP....35.1222V. doi:10.1063/1.1713597.
^ Caesium bromide. nlm.nih.gov
^ Schulz, L. G. (1951). "Polymorphism of cesium and thallium halides". Acta Crystallographica. 4 (6): 487–489. Bibcode:1951AcCry...4..487S. doi:10.1107/S0365110X51001641.

* Crystran Ltd experimental data July 2021 Archived 2012-12-18 at the Wayback Machine

Cited sources

Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, Florida: CRC Press. ISBN 1-4398-5511-0.

External links

MSDS at Oxford University Archived 2007-10-17 at the Wayback Machine
Crystran Physical data Archived 2012-12-18 at the Wayback Machine, IR transmission spectrum
Ultra-violet photoabsorption measurements in alkali iodide and caesium bromide evaporated films

[r1-1] Haynes, p. 4.57

[2] Haynes, p. 4.132

[3] Haynes, p. 10.240

[str2-4] Vallin, J.; Beckman, O.; Salama, K. (1964). "Elastic Constants of CsBr and CsI from 4.2K to Room Temperature". Journal of Applied Physics. 35 (4): 1222. Bibcode:1964JAP....35.1222V. doi:10.1063/1.1713597.

[5] Caesium bromide. nlm.nih.gov

[str-6] Schulz, L. G. (1951). "Polymorphism of cesium and thallium halides". Acta Crystallographica. 4 (6): 487–489. Bibcode:1951AcCry...4..487S. doi:10.1107/S0365110X51001641.

[1]

[2]

[3]

[4]

[5]

[6]

Names


IUPAC name Cesium bromide
Other names Cesium bromide, Caesium(I) bromide
Identifiers
CAS Number	7787-69-1^Y
3D model (JSmol)	Interactive image
ChemSpider	22994^Y
ECHA InfoCard	100.029.209
EC Number	232-130-0
PubChem CID	24592
RTECS number	FK9275000
UNII	06M25EDM3F
CompTox Dashboard (EPA)	DTXSID8064854
InChI InChI=1S/BrH.Cs/h1H;/q;+1/p-1^Y Key: LYQFWZFBNBDLEO-UHFFFAOYSA-M^Y InChI=1/BrH.Cs/h1H;/q;+1/p-1 Key: LYQFWZFBNBDLEO-REWHXWOFAA
SMILES [Cs+].[Br-]
Properties
Chemical formula	CsBr
Molar mass	212.809 g/mol^[1]
Appearance	White solid
Density	4.43 g/cm³^[1]
Melting point	636 °C (1,177 °F; 909 K)^[1]
Boiling point	1,300 °C (2,370 °F; 1,570 K)^[1]
Solubility in water	1230 g/L (25 °C)^[1] Disputed. 420 g/L (11 °C) See References 560 /L (15°C) 1020 g/L (28.5 °C) 1180 g/L (31 °C) 1240 g/L (32.5 °C) 1380 g/L (35 °C)
Magnetic susceptibility (χ)	-67.2·10⁻⁶ cm³/mol^[2]
Refractive index (n_D)	1.8047 (0.3 μm) 1.6974 (0.59 μm) 1.6861 (0.75 μm) 1.6784 (1 μm) 1.6678 (5 μm) 1.6439 (20 μm)^[3]
Structure
Crystal structure	CsCl, cP2
Space group	Pm3m, No. 221^[4]
Lattice constant	a = 0.4291 nm
Lattice volume (V)	0.0790 nm³
Formula units (Z)	1
Coordination geometry	Cubic (Cs⁺) Cubic (Br⁻)
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302, H315, H319, H335
Precautionary statements	P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)	2 0 0
Flash point	Non-flammable
Lethal dose or concentration (LD, LC):
LD₅₀ (median dose)	1400 mg/kg (oral, rat)^[5]
Related compounds
Other anions	Caesium fluoride Caesium chloride Caesium iodide Caesium astatide
Other cations	Sodium bromide Potassium bromide Rubidium bromide Francium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Y verify (what is ^YN ?) Infobox references